To find the average mass of an element you add the mass of each isotope multiplied by it's relative abundance.
[(mass of Cuā¶Ā³)x(relative abundance of Cuā¶Ā³)] + [(mas of Cuā¶āµ)x(relative abundance of Cuā¶āµ0)]= average mass of Cu
[(62.9296)x(.6917)] + [(64.9278)x(.3083)] = 63.54amu