The acid-dissociation constantof hydrocyanic acid (hcn) at 25.0c is 4.9x10-10. what is the ph of an aqueous solution of 0.090 m sodium cyanide (nacn)?

Respuesta :

The pH of an aqueous solution is 11.11

What is pH ?

The pH scale, which previously stood for "potential of hydrogen," is used to describe how acidic or basic an aqueous solution is. The pH values of acidic solutions are typically lower than those of basic or alkaline solutions.

            CN-  + H2O ↔ HCN  + OH-

initial  0.09                        0          0

change -X                        +X          +X

Equ    (0.09-X)                    X            X

so from the equilibrium equation, we can get Ka expression

when Ka = [HCN] [OH-]/[CN-]

when Ka = Kw/Kb

              = (1 x 10^-14) / (4.9 x 10^-10)

              = 2 x 10^-5

So, by substitution:

2 x 10^-5 = X^2 / (0.09 - X)

X= 0.0013

∴ [OH] = X = 0.0013

∴ POH = -㏒[OH]

           = -㏒0.0013

           = 2.886

∴ PH = 14 - POH

        = 14 - 2.886 = 11.11

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