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The 10 ml of salt dissolves more readily than the 30 ml of salt because 10 ml of salt is a lesser amount that needs to dissolve. The salt's bonds are more easily broken at higher temperatures, the salt would dissolve much more readily if the water were warmer.
The ionic link that held sodium and chloride ions together is broken when water molecules force the ions apart. As seen in this picture, the sodium and chloride atoms are encircled by water molecules after the salt compounds are separated. After that, the salt dissolves and forms a homogenous solution. With rising temperatures, most solids, including salt and sugar, become more soluble. Heat causes molecules to travel more quickly, which results in more collisions between the water molecules and the solid.
The majority of salts become more soluble as the temperature rises. This is due to the fact that as the temperature rises, the kinetic energy of the molecules rises and the solvent molecules are better able to dissociate the intermolecularly attracted solute molecules.
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