Calculate the Rf value of compounds X and Y based on information (X travels 0.5.0 cm, Y travels 1.0 cm from the origin line; the solvent front is 3.0 cm). Comment on the polarity and separation of X and Y on the TLC plate.

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Answer:

Retention factor or [tex]R_f[/tex] value is defined as the ratio of distance traveled by the unknown to the distance traveled by the solvent front.

[tex]R_f=\frac{\text{ distance by unknown}}{\text {distance by solvent}}[/tex]

Putting in the values we get:

[tex]R_f_{X}=\frac{0.50cm}{3.0cm}=0.16[/tex]

[tex]R_f_{Y}=\frac{1.0cm}{3.0cm}=0.33[/tex]

As the [tex]R_f[/tex] value of Y is more than X , it follows that Y compound will be retained less strongly than the compound X. Thus Y is more polar than X.