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The difference between Cracking and Pyrolysis in the former is the process of whereby complex organic molecules such as kerogen or long chain hydrocarbon are broken into a simpler molecule while the later is a thermochemical decomposition of organic material at elevated temperature in the absence of oxygen.
The difference between cracking and pyrolysis is that cracking is the breakdown of large organic compounds by use of a catalyst and low temperatures to form fewer different compounds. In Pyrolysis, it's the decomposition of a compound on heating in absence of air.